20–23 Sept 2023
Metropol Lake Resort, Ohrid
Europe/Skopje timezone

Microstructural analysis of thermally treated geopolymer incorporated with neodymium

Not scheduled
20m
Metropol Lake Resort, Ohrid

Metropol Lake Resort, Ohrid

Poster presentation

Speaker

Sanja Knežević (Department of Materials, Vinča Institute of Nuclear Sciences, National Institute of the Republic of Serbia, University of Belgrade, Mike Petrović Alasa 12-14, Belgrade, Serbia)

Description

The following investigation presents the thermal treatment of geopolymer based on metakaolin, with the addition of 1% and 5% of neodymium in the form Nd2O3, at 300˚C, 600˚C and 900˚C. Six samples were synthesized in total. Samples GT1 and GT2 containing 1% and 5% of Nd2O3, and they were treated at 300˚C, while the samples GT3 and GT4 also had the same percentage composition of Nd2O3 and were treated at 600˚C, and the samples GT5 and GT6 were treated at 900˚C with the same percentage of Nd2O3. Physical and chemical changes in the aluminosilicate geopolymer matrix were monitored. The incorporation of rare earths into the polymer network of aluminosilicates has been proven to disrupt the basic structure of geopolymers, however, with increased temperature, these materials show even more unusual properties. DRIFT was employed to investigate the structural properties of thermally treated geopolymers. Additionally, TEM provided further insight into the structural changes induced by thermal treatment and Nd2O3 doping. SEM was used to observe the effect of thermal treatment temperature (300˚C and 600˚C) on geopolymer porosity, which resulted in the appearance of large pores and cracks in the material. The UV/Vis spectra of the synthesized Nd3+doped geopolymers exhibited attractive optical properties. The photoexcitation of electrons from the valence band to the conduction band in the geopolymer structure is responsible for the absorbance observed at 260 nm, while the minor peaks at slightly longer wavelengths can be linked to Nd3+.

Keywords: Geopolymers, Rare earth, Neodymium, Metakaolin, DRIFT, UV/Vis

Primary author

Sanja Knežević (Department of Materials, Vinča Institute of Nuclear Sciences, National Institute of the Republic of Serbia, University of Belgrade, Mike Petrović Alasa 12-14, Belgrade, Serbia)

Co-authors

Dr Danilo KIsić (Department of Atomics Physics, Vinča Institute of Nuclear Sciences, National Institute of the Republic of Serbia, University of Belgrade, Mike Petrović Alasa 12-14, Belgrade, Serbia) Dr Jelena Potočnik (Department of Atomics Physics, Vinča Institute of Nuclear Sciences, National Institute of the Republic of Serbia, University of Belgrade, Mike Petrović Alasa 12-14, Belgrade, Serbia) Dr Marija Ivanović (Department of Materials, Vinča Institute of Nuclear Sciences, National Institute of the Republic of Serbia, University of Belgrade, Mike Petrović Alasa 12-14, Belgrade, Serbia) Dr Miloš Nenadović (Department of Atomics Physics, Vinča Institute of Nuclear Sciences, National Institute of the Republic of Serbia, University of Belgrade, Mike Petrović Alasa 12-14, Belgrade, Serbia) Dr Snežana Nenadović (Department of Materials, Vinča Institute of Nuclear Sciences, National Institute of the Republic of Serbia, University of Belgrade, Mike Petrović Alasa 12-14, Belgrade, Serbia)

Presentation materials