20–23 Sept 2023
Metropol Lake Resort, Ohrid
Europe/Skopje timezone

Glyceline as a safe purification agent of crude biodiesel produced from inedible oil under mild conditions

Not scheduled
20m
Metropol Lake Resort, Ohrid

Metropol Lake Resort, Ohrid

Poster presentation

Speaker

Prof. Zoran Todorović (Faculty of Technology, University of Niš, Leskovac, Serbia)

Description

Natural deep eutectic solvent glyceline, constituted of choline chloride and glycerol in a 1:2 molar ratio, was tested for the purification of crude biodiesel. Low-acid value expired sunflower oil (0.61 mg KOH/g) was used as a feedstock for biodiesel production, prepared by the CaO-catalyzed oil methanolysis carried out at the methanol-to-oil molar ratio of 6:1, CaO amount 2.5% to oil, reaction temperature of 60 °C, stirring rate 900 min-1, and reaction time of 4 h. The phases of the final reaction mixture were separated by centrifugation at 3500 rpm for 10 min. The upper layer was decanted into a flask and evaporated to constant mass under a vacuum at 40 °C using a rotary evaporator to remove unreacted methanol and other volatile impurities. Glyceline was mixed with the crude biodiesel at a 1:1 mass ratio in a two-necked glass flask equipped with a magnetic stirrer, thermometer, and reflux condenser. The purification was conducted at 25 °C and a stirring rate of 700 rpm. The samples were taken after 60, 90, and 120 min, centrifuged, and cooled in a refrigerator at 4 °C to allow separation of glyceline and biodiesel phases. The purest biodiesel was obtained after 120 min and constituted 98.9% fatty acid methyl esters, 0.1% monoacylglycerols, 0.05% diacylglycerols, and 0.15% triacylglycerols. This study suggests glyceline as a safe, natural, and efficient solvent for purifying impure crude biodiesel under moderate conditions.

Primary authors

Dr Dragan Troter (Faculty of Technology, University of Niš, Leskovac, Serbia) Prof. Zoran Todorović (Faculty of Technology, University of Niš, Leskovac, Serbia) Dr Dušica Đokić-Stojanović (Pharmaceutical and Chemical Industry Zdravlje AD, Leskovac, Serbia) Dr Biljana Đorđević (Faculty of Technology, University of Niš, Leskovac, Serbia) Prof. Vlada Veljković (Faculty of Technology, University of Niš, Leskovac, Serbia;Serbian Academy of Sciences and Arts, Belgrade, Serbia)

Presentation materials