27–28 Oct 2025
Faculty of Technology and Metallurgy, Skopje
Europe/Skopje timezone

Investigation of siloxane film on modified silicate glass obtained from TEOS in dry toluene solution

Not scheduled
20m
Amphitheatre (Faculty of Technology and Metallurgy, Skopje )

Amphitheatre

Faculty of Technology and Metallurgy, Skopje

Rugjer Boshkovikj 16, 1000 Skopje

Speaker

Vladimir Grujovski (Institute of Chemistry, Faculty of Natural Sciences and Mathematics Ss. Cyril and Methodius University in Skopje, Arhimedova 5, 1000 Skopje, Macedonia)

Description

Soda-lime-silica glass is widely utilized in industrial and domestic applications. In certain cases, changes in the surface properties are needed. This study investigates the surface modification of soda-lime-silica glass using tetraethyl orthosilicate (TEOS) dissolved in dry toluene and employing dip-coating method.
The modified surfaces were characterized using a range of analytical techniques and methods: contact angle measurements, ratio-reflectance and 2T2D correlation spectra obtained from the measured specular-reflectance FTIR spectra and isoelectric point to evaluate alterations in surface charge. Additionally, AFM was used to examine surface morphology.
Results indicate successful glass surface modification with TEOS and interesting morphology of the film, leading to a very small increase in the water contact angle. These findings suggest that glass surface modification with TEOS from dry toluene as solvent, covers and shields the glass surface, while retaining the hydrophilicity.

Primary author

Vladimir Grujovski (Institute of Chemistry, Faculty of Natural Sciences and Mathematics Ss. Cyril and Methodius University in Skopje, Arhimedova 5, 1000 Skopje, Macedonia)

Co-authors

Prof. Tanja Deckert-Gaudig (Institut für Physikalische Chemie, Friedrich-Schiller-Universität Jena, Lessingstr. 10 07743 Jena, Germany) Prof. Vladimir Ivanovski (Institute of Chemistry, Faculty of Natural Sciences and Mathematics Ss. Cyril and Methodius University in Skopje, Arhimedova 5, 1000 Skopje, Macedonia)

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